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Blair F. Jones

Publications and source records attributed to Blair F. Jones.

12 recordsLinked to original sources
USGS2011

Environmental influences on the occurrences of sepiolite and palygorskite: a brief review

Sepiolite is a hydrous magnesium silicate formed by precipitation of near-surface brackish or saline waters, under semi-arid climatic conditions. Four major influences on the distribution of sepiolite are source materials, climate, physical parameters and associated phase relations. Two major pathways governing the occurrence of sepiolite and palygorskite are direct precipitation from solution, and the transformation of precursor phases by dissolution–precipitation. Sepiolite is most commonly found as a result of the former process, whereas palygorskite is often characterized as a product of the latter. Thus, sepiolite typically occurs in lacustrine, often saline, strata, while palygorskite is commonly found in conjunction with soils, alluvium, or most abundantly, calcretes. Here, we review briefly some examples of sepiolite deposits in Spain, Turkey, Argentina, USA, and the African countries of Kenya, Morocco, Tunisia, Senegal, Somalia and South Africa.

Book chapter↗
USGS2010

Chemical evolution of groundwater near a sinkhole lake, northern Florida: 2. Chemical patterns, mass-transfer modeling, and rates of chemical reactions

Chemical patterns along evolutionary groundwater flow paths in silicate and carbonate aquifers were interpreted using solute tracers, carbon and sulfur isotopes, and mass balance reaction modeling for a complex hydrologic system involving groundwater inflow to and outflow from a sinkhole lake in northern Florida. Rates of dominant reactions along defined flow paths were estimated from modeled mass transfer and ages obtained from CFC-modeled recharge dates. Groundwater upgradient from Lake Barco remains oxic as it moves downward, reacting with silicate minerals in a system open to carbon dioxide (CO 2 ), producing only small increases in dissolved species. Beneath and downgradient of Lake Barco the oxic groundwater mixes with lake water leakage in a highly reducing, silicate-carbonate mineral environment. A mixing model, developed for anoxic groundwater downgradient from the lake, accounted for the observed chemical and isotopic composition by combining different proportions of lake water leakage and infiltrating meteoric water. The evolution of major ion chemistry and the 13 C isotopic composition of dissolved carbon species in groundwater downgradient from the lake can be explained by the aerobic oxidation of organic matter in the lake, anaerobic microbial oxidation of organic carbon, and incongruent dissolution of smectite minerals to kaolinite. The dominant process for the generation of methane was by the CO 2 reduction pathway based on the isotopic composition of hydrogen (δ 2 H(CH 4 ) = −186 to −234‰) and carbon (δ 13 C(CH 4 ) = −65.7 to −72.3‰). Rates of microbial metabolism of organic matter, estimated from the mass transfer reaction models, ranged from 0.0047 to 0.039 mmol L −1 yr −1 for groundwater downgradient from the lake.

Water Resources Research↗
USGS2009

Pore-water chemistry from the ICDP-USGS coer hole in the Chesapeake Bay impact structure--Implications for paleohydrology, microbial habitat, and water resources

We investigated the groundwater system of the Chesapeake Bay impact structure by analyzing the pore-water chemistry in cores taken from a 1766-m-deep drill hole 10 km north of Cape Charles, Virginia. Pore water was extracted using high-speed centrifuges from over 100 cores sampled from a 1300 m section of the drill hole. The pore-water samples were analyzed for major cations and anions, stable isotopes of water and sulfate, dissolved and total carbon, and bioavailable iron. The results reveal a broad transition between fresh and saline water from 100 to 500 m depth in the post-impact sediment section, and an underlying syn-impact section that is almost entirely filled with brine. The presence of brine in the lowermost post-impact section and the trend in the dissolved chloride with depth suggest a transport process dominated by molecular diffusion and slow, compaction-driven, upward flow. Major ion results indicate residual effects of diagenesis from heating, and a pre-impact origin for the brine. High levels of dissolved organic carbon (6-95 mg/L) and the distribution of electron acceptors indicate an environment that may be favorable for microbial activity throughout the drilled section. The concentration and extent of the brine is much greater than had previously been observed, suggesting its occurrence may be common in the inner crater. However, groundwater flow conditions in the structure may reduce the salt-water-intrusion hazard associated with the brine.

Special Paper of the Geological Society of America↗
USGS2008

Geochemical Evolution of Great Salt Lake, Utah, USA

"The Great Salt Lake (GSL) of Utah, USA, is the largest saline lake in North America, and its brines are some of the most concentrated anywhere in the world. The lake occupies a closed basin system whose chemistry reflects solute inputs from the weathering of a diverse suite of rocks in its drainage basin. GSL is the remnant of a much larger lacustrine body, Lake Bonneville, and it has a long history of carbonate deposition. Inflow to the lake is from three major rivers that drain mountain ranges to the east and empty into the southern arm of the lake, from precipitation directly on the lake, and from minor groundwater inflow. Outflow is by evaporation. The greatest solute inputs are from calcium bicarbonate river waters mixed with sodium chloride-type springs and groundwaters. Prior to 1930 the lake concentration inversely tracked lake volume, which reflected climatic variation in the drainage, but since then salt precipitation and re-solution, primarily halite and mirabilite, have periodically modified lake-brine chemistry through density stratification and compositional differentiation. In addition, construction of a railway causeway has restricted circulation, nearly isolating the northern from the southern part of the lake, leading to halite precipitation in the north. These and other conditions have created brine differentiation, mixing, and fractional precipitation of salts as major factors in solute evolution. Pore fluids and diagenetic reactions have been identified as important sources and especially sinks for CaCO3, Mg, and K in the lake, depending on the concentration gradient and clays."

Aquatic Geochemistry↗
USGS2003

Transient and steady-state salt transport between sediments and brine in closed lakes

A diffusional transport model for Lake Abert, Oregon, predicts the rates of salt transport from pore fluids into lake waters. In a lake without outflow dissolved salts may migrate across the sediment-water interface in response to a concentration difference between lake and interstitial brine. Transport of salt upward is transient; its direction can be reversed by external input of salt or by depletion of salts stored in the sediments, and a steady-state concentration in lake water is not attainable. Downward transport can be a stationary process if the sedimentation rate is rapid compared with molecular diffusion of salt in interstitial brine, but characteristic rates arc too slow to lead to steady-state concentrations within the lifetime of a closed lake. In Lake Abert, diffusional flux upward was much more important than input of salt from other sources; 45% of the salt of lake brine in 1963–1964 was added from the sediment pore space during the preceding 25 years, only 0.1% from external inflow. The sediment source will dominate input during high water level. Such models permit comparison of salt transport across the sediment-water interface with other input sources at different times of the lake’s history.

Oregon↗
USGS1976

WATEQF; a FORTRAN IV version of WATEQ : a computer program for calculating chemical equilibrium of natural waters

WATEQF is a FORTRAN IV computer program that models the thermodynamic speciation of inorganic ions and complex species in solution for a given water analysis. The original version (WATEQ) was written in 1973 by A. H. Truesdell and B. F. Jones in Programming Language/one (PL/1.) With but a few exceptions, the thermochemical data, speciation, coefficients, and general calculation procedure of WATEQF is identical to the PL/1 version. This report notes the differences between WATEQF and WATEQ, demonstrates how to set up the input data to execute WATEQF, provides a test case for comparison, and makes available a listing of WATEQF. (Woodard-USGS)

Water-Resources Investigations Report↗
USGS1974

WATEQ, a computer program for calculating chemical equilibria of natural waters

The computer program, WATEQ, calculates the equilibrium distribution of inorganic aqueous species of major and important minor elements in natural waters using the chemical analysis and in situ measurements of temperature, pH, and redox potential. From this model, the states of reaction of the water with solid and gaseous phases are calculated. Thermodynamic stabilities of aqueous species, minerals, and gases have been selected from a careful consideration of all available experimental data. The program is written in PL-1 for IBM 360 computers.

Journal of Research of the U.S. Geological Survey↗
USGS1972

Significance of ground-water chemistry in performance of North Sahara Tube wells in Algeria and Tunisia

Nine ground-water samples from the principal shallow and deep North Sahara aquifers of Algeria and Tunisia were examined to determine the relation of their chemical composition to corrosion and mineral encrustation thought to be contributing to observed decline in well capacities within a UNESCO/UNDP Special Fund Project area. Although the shallow and deep waters differ significantly in certain quality factors, all are sulfochloride types with corrosion potentials ranging from moderate to extreme. None appear to be sufficiently supersaturated with troublesome mineral species to cause rapid or severe encrustation of filter pipes or other well parts. However, calcium carbonate encrustation of deep-well cooling towers and related irrigation pipes can be expected because of loss of carbon dioxide and water during evaporative cooling. Corrosion products, particularly iron sulfide, can be expected to deposit in wells producing waters from the deep aquifers. This could reduce filterpipe openings and increase casing roughness sufficiently to cause significant reduction in well capacity. It seems likely, however, that normal pressure reduction due to exploitation of the artesian systems is a more important control of well performance. If troublesome corrosion and related encrustation are confirmed by downhole inspection, use of corrosion-resisting materials, such as fiber-glass casing and saw-slotted filter pipe (shallow wells only), or stainless-steel screen, will minimize the effects of the waters represented by these samples. A combination of corrosion-resisting stainless steel filter pipe electrically insulated from the casing with a nonconductive spacer and cathodic protection will minimize external corrosion of steel casing, if this is found to be a problem. However, such installations are difficult to make in very deep wells and difficult to control in remote areas. Both the shallow waters and the deep waters examined in this study will tend to cause soil salinization because their salt contents are relatively high, and both have sodium absorption ratios which are unfavorable to sodium-sensitive soils and vegetation. Proper drainage and soil treatment are the only means of overcoming these problems during irrigation.

Water Supply Paper↗