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Geology topics

Barney J. Szabo

Publications and source records attributed to Barney J. Szabo.

At least 37 records · Page 2Linked to original sources

Uranium-series nuclides in the Golden fault, Colorado, U.S.A.: Dating latest fault displacement and measuring recent uptake of radionuclides by fault-zone materials

Concentrations and isotopic ratios of U, Th and Ra were measured in a fault zone near Golden, Colorado where major displacement occurred between about 190 and 615 ka. Faulting created new surfaces for leaching and provided the pathways for U-rich ground water. Uranium and 230 Th, the latter produced by the decay of dissolved 234 U, are adsorbed by fault gouge, hematite-stained sand and brecciated sand- and claystones. The observed U enrichment is as much as six times baseline value and the simultaneous enrichment of 230 Th is estimated at about ninefold relative to 238 U. The adsorption of radionuclides chemically analogous to Th, such as Pu (IV) and Np, and 237 Np decay products, on fault-zone materials would contribute to the immobilization of high-level radioactive waste in the vicinity of a repository in the event of leakage from engineered barriers into fractured rock-mass.

Colorado

Uranium-series dated authigenic carbonates and Acheulian sites in southern Egypt

Field investigations in southern Egypt have yielded Acheulian artifacts in situ in authigenic carbonate deposits (CaCO 3 -cemented alluvium) along the edges of now-aggraded paleovalleys (Wadi Arid and Wadi Safsaf). Uranium-series dating of 25 carbonate samples from various localities as far apart as 70 kilometers indicates that widespread carbonate deposition occurred about 45, 141 and 212 ka (thousand years ago). Most of the carbonate appears to have been precipitated from groundwater, which suggests that these three episodes of deposition may be related to late Pleistocene humid climates that facilitated human settlement in this now hyperarid region. Carbonate cements from sediments containing Acheulian artifacts provide a minimum age of 212 ka for early occupation of the paleovalleys.

southern Egypt

A 250,000-year climatic record from Great Basin vein calcite: Implications for Milankovitch theory

A continuous record of oxygen-18 (δ 18 O) variations in the continental hydrosphere during the middle-to-late Pleistocene has been obtained from a uranium-series dated calcitic vein in the southern Great Basin. The vein was deposited from ground water that moved through Devils Hole—an open fault zone at Ash Meadows, Nevada—between 50 and 310 ka (thousand years ago). The configuration of the δ 18 O versus time curve closely resembles the marine and Antarctic ice core (Vostok) δ 18 O curves; however, the U-Th dates indicate that the last interglacial stage (marine oxygen isotope stage 5) began before 147 ± 3 ka, at least 17,000 years earlier than indicated by the marine δ 18 O record and 7,000 years earlier than indicated by the less well dated Antarctic δ 18 O record. This discrepancy and other differences in the timing of key climatic events suggest that the indirectly dated marine δ 18 O chronology may need revision and that orbital forcing may not be the principal cause of the Pleistocene ice ages.

Nevada

Age of -360-m reef terrace, Hawaii, and the rate of late Pleistocene subsidence of the island

Observations from a manned submersible vehicle indicate that the −360-m reef terrace northwest of the island of Hawaii is a drowned coral reef. The preferred uranium-series age of coralline algae collected from the reef face is 120 ± 5 ka. This age agrees with the notion that the reef was drowned during the sea-level rise following the major lowstand of the sea that occurred at 145 ka (oxygen isotope stage 6). This drowning pattern is similar to the previously determined radiocarbon age of 13 ka for drowning of the −150-m reef off west Hawaii, which drowned during the sea-level rise following the last major lowstand of the sea at 18 ka (oxygen isotope stage 2). Estimated average subsidence of the reef site off northwest Hawaii is 2.7 mm/yr since final drowning of the −360-m reef.

Hawaii

Rock-water interaction in ash-flow tuffs (Yucca Mountain, Nevada, USA)- The record from uranium studies

Forty-eight core samples of ash-flow tuffs from Yucca Mountain, NV, were selected for comparative analysis by uranium-based methods to estimate past interaction with oxidizing water. Results aid in the selection of hydrologically isolated host rocks for radioactive waste disposal. U abundances were consistently more variable than thorium in whole rocks, suggesting some selective redistribution of U. Dissolved U correlates most strongly with dissolved manganese, indicating a predominant association of U with manganese oxides.

Nevada

Two-million-year record of deuterium depletion in Great Basin ground waters

Fluid inclusions in uranium series-dated calcitic veins from the southern Great Basin record a reduction of 40 per mil in the deuterium content of groundwater recharge during the Pleistocene. This variation is tentatively attributed to major uplift of the Sierra Nevada Range and the Transverse Ranges during this epoch with attendant increasing orographic depletion of deuterium from inlandbound Pacific storms.

Sierra Nevada Range

Uranium-series dating of fossil corals from marine sediments of southeastern United States Atlantic Coastal Plain

Extensive low-lying marine deposits border the southeastern United States Atlantic Coastal Plain. Some units are fossiliferous and contain corals as isolated fragments in sediments of a detrital character. These corals are subject to alteration processes such that suites of related samples must be examined to determine the suitability of these coral samples for reliable uranium-series dating. With the exception of those from one location, most samples appear to have remained closed systems with respect to the isotopes of uranium and thorium throughout their geologic history. Extraneous 230 Th has been detected in some of the corals due to incorporation of some detrital materials into their skeletons. For these samples, different methods are applied to correct for the initial 230 Th contamination. Continued sampling and analyses have resulted in 55 individual uranium-thorium determinations. The average 230 Th ages of samples from the Norfolk Formation, and from later- and earlier-deposited sediments of the Wando Formation are ∼71,000, 87,000, and 129,000 yr, and they appear to correlate with oxygen isotope substages 5a, 5c, and 5e, respectively. The average 230 Th age of samples from beds of the Rappahannock River, Ponzer, and Ten Mile Hill localities is ∼212,000 yr, and they correlate with oxygen isotope stage 7. The sediment of the Canepatch Formation is ∼460,000, yr old, and it is tentatively correlated with oxygen isotope stage 11. There is general agreement between uranium-series and uranium-trend dates and between the quantitative trends of the amino acid data and uranium-series dates. The amino acid values, however, ure unacceptably high in at least two groups of samples, those from localities near Charleston, South Carolina, and from central Virginia.

Geological Society of America Bulletin

Age determination of late Pleistocene marine transgression in western Alaska

Dating molluscs from sediments representing the Kotzebuan marine transgression in Alaska yields an average uranium-series age of 104,000 ± 22,000 yrs B.P. This and other selected Pleistocene marine deposits of western Alaska are tentatively correlated with radiometrically dated units of eastern Baffin Island, Arctic Canada.

Alaska

Stratigraphy, structure, absolute age, and paleontology of the upper Pleistocene deposits at Sankaty Head, Nantucket Island, Massachusetts

The Sankaty Head cliff exposes drift of at least two glaciations and interglacial marine deposits. Radiocarbon, amino-acid- racemization, and uranium-thorium analyses were used to determine the absolute ages of the beds. The results indicate that 1) the Sankaty Sand correlates with oxygen-isotope stage 5 (Sangamonian), 2) the underlying drift is older than stage 5 (Illinoian or older) , and 3) the overlying drift is Wisconsinan in age. -from Authors

Massachusetts

Uranium-series dating of mollusks and corals, and age of Pleistocene deposits, Chesapeake Bay area, Virginia and Maryland

Geologic mapping in conjunction with uranium-series dating of fossil mollusks and corals suggests that the low-lying ( < 17 m in altitude) terrace deposits in the central and southern Chesapeake Bay area include two main depositional sequences, each of which represents a high stand of the sea in late Pleistocene time. The older depositional sequence includes the Accomack and Omar beds of the Delmarva area, the fossiliferous deposits along the lower Rappahannock River, and the Norfolk Formation deposits west of the Suffolk scarp. These beds have yielded a single reliable coral age estimate of 184,000?20,000 years B.P., suggesting an early late Pleistocene age. The younger sequence, including the type beds of the Norfolk Formation and equivalent strata east of the Suffolk scarp, has yielded several coral ages ranging from about 62,000 to 86,000 years B.P. (including ages from our samples and previously reported age estimates); thus, it is clearly late Pleistocene in age. Groupings of ages obtained from our quahog analyses also suggest two transgressive sequences; however, the estimated quahog ages are consistently younger than ages based on coral samples from the same and equivalent stratigraphic units. Stratigraphic, paleoclimatic, and geomorphic data suggest that the estimated uranium-series age of 71,000?7,000 years B.P. for the type beds of the Norfolk, obtained by averaging our coral dates, may be too young by as much as several tens of thousands of years. A postulated equivalency of the type Norfolk beds, upper Pleistocene deposits near Charleston, S.C. (apparent uranium-series age = 95,000?5,000 years), and deposits in the Caribbean area thought to represent the highest sea stand during the last interglacial period (apparent age, 125,000?10,000 years) implies diagenetic modification of coralline material possibly in part because of regional differences in depositional and postdepositional environments.

Professional Paper

Quaternary climates and sea levels of the U.S. Atlantic Coastal Plain

Uranium-series dating of corals from marine deposits of the U.S. Atlantic Coastal Plain coupled with paleoclimatic reconstructions based on ostracode (marine) and pollen (continent) data document at least five relatively warm intervals during the last 500,000 years. On the basis of multiple paleoenvironmental criteria, we determined relative sea level positions during the warm intervals, relative to present mean sea level, were 7 ± 5 meters at 188,000 years ago, 7.5 ± 1.5 meters at 120,000 years ago, 6.5 ± 3.5 meters at 94,000 years ago, and 7 ± 3 meters at 72,000 years ago. The composite sea level chronology for the Atlantic Coastal Plain is inconsistent with independent estimates of eustatic sea level positions during interglacial intervals of the last 200,000 years. Hydroisostatic adjustment from glacial-interglacial sea level fluctuations, lithospheric flexure, and isostatic uplift from sediment unloading due to erosion provide possible mechanisms to account for the discrepancies. Alternatively, current eustatic sea level estimates for the middle and late Quaternary may require revision.

Atlantic Coastal Plain

Comparison of uranium-series, radiocarbon, and amino acid data from marine molluscs, Baffin Island, Arctic Canada

Uranium-series and 14 C dates and the extent of amino acid racemization are reported for 24 marine shell samples from three areas of Baffin Island, Arctic Canada. When the radiometric dates are plotted against the ratio of D-alloisoleucene:L-isoleucene in the shells, five broad age groups are recognized. The uranium-series data indicate that 231 Pa is incompletely retained in most fossil shells and that 230 Th is lost from some of the samples. Therefore, their apparent ages are minimum. However, a few dated samples in each group have yielded useful age results, and the minimum ages of the five groups of samples are estimated as 7,000 to 11,000, ≥ 70,000, ≥ 136,000, ≥ 190,000, and > 300,000 yr. Calculated integrated thermal histories based on the epimerization reaction in the mollusc Hiatella arctica Linné give paleotemperature estimates of around −5 °C, compared to the present mean annual air temperature of about −11 °C.

Baffin Island

Results and assessment of uranium series dating of vertebrate fossils from Quaternary alluvium in Colorado

An average uranium-series age of 102,000 ± 14,000 yr for bones from Louviers Alluvium, near Denver, Colorado, is compatible with the inferred geologic age of from 120,000 to 150,000 yr. A uranium-series date of about 190,000 yr for a bone from Slocum Alluvium, near Canon City, Colorado, is consistent with the inferred geologic age of from 150,000 to 260,000 yr. Age determinations for the Broadway Alluvium are inconsistent but its geologic age is considered to be 15,000 to 30,000 yr BP.

Colorado

Uranium-series age of coral reef growth on Rottnest Island, Western Australia

Dating samples of corals and shell from the elevated coral reef terrace on Rottnest Island, Western Australia, indicate that in this region away from active plate boundaries the sea stood at least 3 m above present sea level 132,000 ± 5,000 years ago. There is no geologic evidence of other ancient reef-forming periods on this island.

Rottnest Island

Pleistocene apparent ages by U-Pb isotope and U-series methods for uranium ore in Dakota Sandstone near Gallup, New Mexico

Radiometric dates of a high-grade uranium ore from the Hogback No. 4 mine in Dakota Sandstone near Gallup, N. Mex., indicate a late Pleistocene age of mineralization. The 206 Pb/ 238 U and 207 Pb/ 235 U apparent ages of about 70 000 yr and 100000 yr, respectively, are discordant, but are in broad agreement with the discordant 230 Th/ 238 U and 231 Pa/ 235 U apparent ages of 130000 yr and 78000 yr, respectively. Although it is not clear how the analyzed sample relates to the main period of mineralization at this mine, these dates are consistent with previous age limits suggested for Dakota Sandstone uranium-ores.

New Mexico