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B. W. Bruce

Publications and source records attributed to B. W. Bruce.

9 recordsLinked to original sources
USGS2007

Contrasting water quality from paired domestic/public supply wells, central High Plains

Closely located domestic and public supply wells were sampled using identical sampling procedures to allow comparison of water quality associated with well type. Water samples from 15 pairs of wells with similar screened intervals completed in the central High Plains regional aquifer in parts of Kansas, Oklahoma, and Texas were analyzed for more than 200 water quality constituents. No statistically significant differences were observed between the concentrations of naturally-derived constituents (major ions, trace elements, and radon) in paired wells. However, differences in water quality between paired wells were observed for selected anthrepogenic compounds (pesticides and tritium), in that some public supply wells produced water that was more recently recharged and contained constituents derived from surface activities. The presence of recently recharged water and compounds indicative of anthrepogenic activities in some public supply wells was likely due to operational variations (pumping rate and pumping cycles), as demonstrated in a particle tracking simulation. Water containing surface-derived anthropogenic compounds from near the water table was more quickly drawn to high volume public supply wells (less than five years) than domestic wells (greater than 120 years) with small pumping rates. These findings indicate that water quality samples collected from different well types in the same area are not necessarily directly comparable. Sampling domestic wells provides the best broad-scale assessment of water quality in this aquifer setting because they are less susceptible to localized contamination from near the water table. However, sampiing public supply wells better represents the quality of the used resource because of the population served.

Kansas, Oklahoma, Texas↗
USGS2007

Climate variability controls on unsaturated water and chemical movement, High Plains aquifer, USA

Responses in the vadose zone and groundwater to interannual, interdecadal, and multidecadal climate variability have important implications for groundwater resource sustainability, yet they are poorly documented and not well understood in most aquifers of the USA. This investigation systematically examines the role of interannual to multidecadal climate variability on groundwater levels, deep infiltration (3–23 m) events, and downward displacement (>1 m) of chloride and nitrate reservoirs in thick (15–50 m) vadose zones across the regionally extensive High Plains aquifer. Such vadose zone responses are unexpected across much of the aquifer given a priori that unsaturated total-potential profiles indicate upward water movement from the water table toward the root zone, mean annual potential evapotranspiration exceeds mean annual precipitation, and millennia-scale evapoconcentration results in substantial vadose zone chloride and nitrate reservoirs. Using singular spectrum analysis (SSA) to reconstruct precipitation and groundwater level time-series components, variability was identified in all time series as partially coincident with known climate cycles, such as the Pacific Decadal Oscillation (PDO) (10–25 yr) and the El Niño/Southern Oscillation (ENSO) (2–6 yr). Using these lag-correlated hydrologic time series, a new method is demonstrated to estimate climate-varying unsaturated water flux. The results suggest the importance of interannual to interdecadal climate variability on water-flux estimation in thick vadose zones and provide better understanding of the climate-induced transients responsible for the observed deep infiltration and chemical-mobilization events. Based on these results, we discuss implications for climate-related sustainability of the High Plains aquifer.

Vadose Zone Journal↗
USGS2006

Storage and transit time of chemicals in thick unsaturated zones under rangeland and irrigated cropland, High Plains, United States

In 2000-2002, three rangeland and six irrigated sites were instrumented to assess the storage and transit time of chemicals in thick (15 to 50 m) unsaturated zones (UZ) in the High Plains. These processes are likely to influence relations between land use and groundwater quality, yet they have not been documented systematically in the High Plains. Land use and climate were important controls on the size of subsoil chloride, nitrate, and pesticide compound reservoirs. The reservoirs under irrigated cropland generally were larger than those under rangeland because more chemicals were applied to cropland than to rangeland. In some cases, chloride and nitrate reservoirs under rangeland were larger than those under cropland, presumably because of long‐term evaporative concentration near the base of the root zone. Natural salts mobilized by irrigation return flow accounted for as much as 60 and 80% of the nitrate and chloride reservoirs, respectively, under some cropland, as indicated by detailed chemical profiles and isotopic tracers ( 15 N, 18 O in nitrate and 2 H, 3 H, 18 O in water). Advective chemical transit times in the UZ under cropland ranged from about 50 to 375 years, longer than any of the instrumented fields had been irrigated, yet agrichemicals were detected at the water table at four of the six sites. The data provide evidence for the existence of slow and fast paths for water movement in the UZ, with larger subsoil chemical reservoirs occurring in areas dominated by slow paths. Implications of these findings with respect to water quality in the aquifer are significant because they indicate that the amount of chemical mass reaching the aquifer could increase with time as chemicals that still reside under irrigated fields reach the water table.

Water Resources Research↗
USGS1996

Shallow ground-water quality beneath a major urban center: Denver, Colorado, USA

A survey of the chemical quality of ground water in the unconsolidated alluvial aquifer beneath a major urban center (Denver, Colorado, USA) was performed in 1993 with the objective of characterizing the quality of shallow ground-water in the urban area and relating water quality to land use. Thirty randomly selected alluvial wells were each sampled once for a broad range of dissolved constituents. The urban land use at each well site was sub- classified into one of three land-use settings: residential, commercial, and industrial. Shallow ground-water quality was highly variable in the urban area and the variability could be related to these land-use setting classifications. Sulfate (SO4) was the predominant anion in most samples from the residential and commercial land-use settings, whereas bicarbonate (HCO3) was the predominant anion in samples from the industrial land-use setting, indicating a possible shift in redox conditions associated with land use. Only three of 30 samples had nitrate concentrations that exceeded the US national drinking-water standard of 10 mg l-1 as nitrogen, indicating that nitrate contamination of shallow ground water may not be a serious problem in this urban area. However, the highest median nitrate concentration (4.2 mg l-1) was in samples from the residential setting, where fertilizer application is assumed to be most intense. Twenty-seven of 30 samples had detectable pesticides and nine of 82 analyzed pesticide compounds were detected at low concentrations, indicating that pesticides are widely distributed in shallow ground water in this urban area. Although the highest median total pesticide concentration (0.17 ??g l-1) was in the commercial setting, the herbicides prometon and atrazine were found in each land-use setting. Similarly, 25 of 29 samples analyzed had detectable volatile organic compounds (VOCs) indicating these compounds are also widely distributed in this urban area. The total VOC concentrations in sampled wells ranged from nondetectable to 23 442 ??g l-1. Widespread detections and occasionally high concentrations point to VOCs as the major anthropogenic ground-water impact in this urban environment. Generally, the highest VOC concentrations occurred in samples from the industrial setting. The most frequently detected VOC was the gasoline additive methyl tertbutyl ether (MTBE, in 23 of 29 wells). Results from this study indicate that the quality of shallow ground water in major urban areas can be related to land-use settings. Moreover, some VOCs and pesticides may be widely distributed at low concentrations in shallow ground water throughout major urban areas. As a result, the differentiation between point and non-point sources for these compounds in urban areas may be difficult.

Journal of Hydrology↗
USGS1993

Water-quantity, water-quality, soil, and sediment data collected at Goose Egg Spring, Natrona County, Wyoming, May and July 1992

Recent, apparent increases in sediment accumulation in Goose Egg Spring, southwest of Casper, Wyoming, may have been the result of natural environmental processes or quarry operations near the spring in late 1991. Goose Egg Spring is the sole source of water for the Dan Speas Fish Rearing Station. This facility is operated by the Wyoming Game and Fish Commission and produces about 77,000 kilograms of stockable fish annually. Samples of the spring water, surrounding soils, and bottom sediment were collected. Methods used in obtaining all samples are discussed. Results of chemical analyses of the spring water, stratigraphic description of core samples, particle-size distribution analysis, visual mineralogical assessment, and X-ray diffraction analysis were used to characterize Goose Egg Spring and the immediately surrounding area in May and July 1992.

Open-File Report↗