Geology topics

B. R. Doe

Publications and source records attributed to B. R. Doe.

23 records · Page 2Linked to original sources

USGS1970

Lead and strontium isotopes in rocks of the Absaroka volcanic field, Wyoming

The Absaroka volcanic field is comprised of predominant andesitic volcaniclastic rocks and less abundant potassium-rich mafic lavas (shoshonites and absarokites). Strontium and lead isotopic variations preclude a simple derivation from an isotopically uniform source: Sr 87 /Sr 86 , 0.7042 to 0.7090; Pb 206 /Pb 204 , 16.31 to 17.30; Pb 208 /Pb 204 , 36.82 to 37.64. We postulate that these rocks were derived from a lower crust or upper mantle which underwent a preferential loss of uranium relative to lead approximately 2800±200 m.y. ago. Variations in lead and strontium isotopic compositions are thought to reflect small inhomogeneities in U/Pb and Rb/Sr ratios in the source.

Wyoming↗

USGS1969

Primitive and contaminated basalts from the Southern Rocky Mountains, U.S.A

Basalts in the Southern Rocky Mountains province have been analyzed to determine if any of them are primitive. Alkali plagioclase xenocrysts armored with calcic plagioclase seem to be the best petrographic indicator of contamination. The next best indicator of contamination is quartz xenocrysts armored with clinopyroxene. On the rocks and the region studied, K 2 O apparently is the only major element with promise of separating primitive basalt from contaminated basalt inasmuch as it constitutes more than 1 % in all the obviously contaminated basalts. K 2 O: lead (> 4 ppm) and thorium (> 2 ppm) contents and Rb/Sr (> 0.035) are the most indicative of the trace elements studied. Using these criteria, three basalt samples are primitive (although one contains 1.7% K 2 O) and are similar in traceelement contents to Hawaiian and Eastern Honshu, Japan, primitive basalts. Contamination causes lead isotope ratios, 206 Pb/ 204 Pb and 208 Pb/ 204 Pb, to become less radiogenic, but it has little or no effect on 87 Sr/ 86 Sr. We interpret the effect on lead isotopes to be due to assimilation either of lower crustal granitic rocks, which contain 5–10 times as much lead as basalt and which have been low in U/Pb and Th/Pb since Precambrian times, or of upper crustal Precambrian or Paleozoic rocks, which have lost much of their radiogenic lead because of heating prior to assimilation. The lack of definite effects on strontium isotopes may be due to the lesser strontium contents of granitic crustal rocks relative to basaltic rocks coupled with lack of a large radiogenic enrichment in the crustal rocks. Lead isotope ratios were found to be less radiogenic in plagioclase separates from an obviously contaminated basalt than in the primitive basalts. The feldspar separate that is rich in sodic plagioclase xenocrysts was found to be similar to the whole-rock composition for 206 Pb/ 204 Pb and 208 Pb/ 204 Pb whereas a more dense fraction probably enriched in more calcic plagioclase phenocrysts is more similar to the primitive basalts in lead isotope ratios. The primitive basalts have: 206 Pb/ 204 Pb ∼ 18.09–18.34, 207 Pb/ 204 Pb ∼ 15.5, 208 Pb/ 204 Pb ∼ 37.6–37.9, 87 Sr/ 86 Sr ∼ 0.704–0.705. In the primitive basalts from the Southern Rocky Mountains the values of 206 Pb/ 204 Pb are similar to values reported by others for Hawaiian and eastern Honshu basalts and abyssal basalts, whereas 208 Pb/ 204 Pb tends to be equal to or a little less radiogenic than those from the oceanic localities. 87 Sr/ 86 Sr appears to be equal to or a little greater than those of the oceanic localities. These 206 Pb/ 204 Pb and 208 Pb/ 204 Pb ratios are distinctly less radiogenic and 87 Sr/ 86 Sr values are about equal to those reported by others for volcanic islands on oceanic ridges and rises.

Colorado↗

USGS1968

Lead and strontium isotope studies of the Boulder Batholith, Southwestern Montana

The isotopic composition of lead in feldspar varies widely from pluton to pluton of the Late Cretaceous Boulder batholith, encompassing the following ranges in isotopic values: 16.9-18.1 for Pb 206 /Pb 204 ; 15.4-15.7 for Pb 207 /Pb 204 ; and 37.7-38.5 for Pb 205 /Pb 204 . Although each pluton has a characteristic isotopic composition, the fact that Pb 206 /Pb 204 for the Butte Quartz Monzonite varies by 1.3 percent, compared to a range of about 8.6 percent for the batholith as a whole, suggests that perfect isotopic mixing of the magma was not always attained. Whole rock initial Sr 87 /Sr 88 for the entire batholith ranges from 0.705 to 0.710, comparable to ranges for the Sierra Nevada and British Columbia batholiths. Ore leads of the Butte district are isotopically very similar to feldspar leads of the host Butte Quartz Monzonite. This isotopic similarity was interpreted by Murthy and Patterson (1961a) to indicate complete mixing of independently derived feldspar lead and ore lead rather than close genetic relationship. However, detailed study of the only sample in the present investigation, from the Donald pluton, that clearly has mixed leads shows significant differences in lead isotopic composition between megacryst K-feldspar and both the groundmass K-feldspar and plagioclase, indicating that isotopic mixing of leads is not complete, even within a single hand specimen. Spatial relations of isotopic differences among the various plutons strongly suggest that complete mixing of leads of different isotopic composition from the magma did not occur in the Butte Quartz Monzonite nor in any other pluton of the batholith, and that the isotopic similarity between Butte ore and feldspar lead of the host rock indeed stems from a genetic association. Lead and strontium isotope ratios generally behave in a similar way; that is, the more radiogenic the lead in a rock, the more radiogenic the strontium. The source of the lead which could produce the isotope variations observed for the batholith is calculated to have a mean age of about 2,200 m.y., which is compatible with ages of Precambrian crystalline rocks in the region, and an isotopic makeup with U 238 /pb 204 <9, Th/U > 4, and Rb/Sr of 0.03-0.09. However, no large volumes of prebatholith rocks exposed in the Boulder batholith region are of the required isotopic composition, which is typical of basaltic-gabbroic or quartz dioritic chemical composition. Models involving complete melting of possible source materials to account for the isotope variations are considered and rejected. Mechanisms involving par.tial melting of lower crustal or upper mantle source material appear to be the most viable in explaining the observed isotopic compositions. Assimilation of upper crustal material (i.e., the Precambrian Belt and pre-Belt rocks, in which the lead and strontium are more radiogenic than in the batholith rocks) may have accompanied partial melting of the lower crust or upper mantle and indeed must have played a major role if the source material had a composition isotopically comparable to that observed for oceanic tholelites (i.e., low Th/U, U 238 /Pb 204 and Rb/Sr), but would be relatively unimportant if the source material were sufficiently radiogenic to begin with as might be expected from basalt, gabbro, or quartz diorite compositions 2,200 m.y. old. © 1968 Society of Economic Geologists, Inc.

Montana↗

USGS1967

Preliminary lead isotope investigations of brine from the Red Sea, Galena from the Kingdom of Saudi Arabia, and galena from United Arab Republic (Egypt)

The isotopic composition of lead in Red Sea chloride brine containing 0.5 ppm Pb is found to be similar to that of some Cenozoic ore leads such as galena at Rabigh in Saudi Arabia that may have formed during mineralization accompanying Tertiary rifting. Bir Ranga galena in Miocene sediments from United Arab Republic (Egypt) is also isotopically similar to lead in Red Sea brine. The chlorine brine must be considered a possible mineralizing fluid. Lead isotopes show promise for use in mineral prospect evaluation in that galena from Samrah is isotopically similar to that from Mahd adh Dhahab, which has been the only ore producer in Saudi Arabia since 1945. Drilling at Samrah does indicate a possible economic mineralization. The lead isotope data coupled with available geologic knowledge and geochronometry are used to tentatively divide the ore prospects of the Kingdom of Saudi Arabia into relative categories of mineralization age. Two Mesozoic and Cenozoic mineralizations are distinguished on the basis of a 207 Pb/ 204 Pb difference; an early Paleozoic mineralization grouping is outlined; and a late Precambrian mineralization period is suggested.

Earth and Planetary Science Letters↗

USGS1966

Preliminary investigation of the source of lead and strontium in deep geothermal brines underlying the Salton Sea geothermal area

A radiogenic tracer study has been made of lead and strontium in deep geothermal brines , salt from brine , and the upper Quaternary rhyolite domes near the Salton Sea in the Imperial Valley, California. The data on the brines and rhyolite glasses are compared to those from Quaternary Colorado River and Tertiary sediments of the area . The brines sampled contain '-'100 ppm Pb, sufficient for consideration as a possible ore-forming fluid. The isotopic data indicate that 80-100 percent of the strontium and 50-100 percent of the lead in these brines were acquired from the associated sediments. The isotopic compositions of lead and strontium in the Quaternary rhyolite glasses are distinctly different from those of the sediments and brines . The strontium data suggest that the rhyolite glasses were derived from basaltic or gabbroic material but may have attained as much as 40 percent of their strontium from upper crustal rocks such as the sediments analyzed.

California↗