Geology topics

Amanda Booth

Publications and source records attributed to Amanda Booth.

7 recordsLinked to original sources

USGS2023

Field techniques for fluorescence measurements targeting dissolved organic matter, hydrocarbons, and wastewater in environmental waters: Principles and guidelines for instrument selection, operation and maintenance, quality assurance, and data reporting

The use of field deployable fluorescence sensors by the U.S. Geological Survey has become increasingly common for a wide variety of surface water and groundwater investigations. This report addresses field deployable fluorometers that measure the fluorescence response of various substances in water exposed to incident light generated by the sensor. An introduction to the basic principles of field measurements of fluorescence is provided, as well as technical background information on sensors that target dissolved organic matter, wastewater, and hydrocarbons, including sensor selection, operating principles, key features, and design elements. General deployment, operation and maintenance protocols, quality-assurance techniques, and suggestions for data reporting are presented to facilitate and standardize the collection and accurate communication of data collected by the U.S. Geological Survey across studies, sites, and sensor types. Sensor performance issues and common interferences are also described. An appendix is included to describe sensor calibration criteria and procedures, reporting units, and specific approaches to correct for interferences for fluorescence of dissolved organic matter sensors.

Techniques and Methods↗

USGS2021

Development and application of surrogate models, calculated loads, and aquatic export of carbon based on specific conductance, Big Cypress National Preserve, south Florida, 2015–17

Understanding the carbon transport within aquatic environments is crucial to quantifying global and local carbon budgets, yet limited empirical data currently (2021) exist. This report documents methodology and provides data for quantifying the aquatic export of carbon from a cypress swamp within Big Cypress National Preserve and is part of a larger carbon budget study. The U.S. Geological Survey operated two continuous monitoring stations, 022889001 and 022909471, that measured flow volume and water quality within the Big Cypress National Preserve in South Florida from September 2015 to October 2017. Station 022889001 represented the flow into the study area and station 022909471 represented the flow out of the study area. Site-specific regression models were developed by using continuously measured specific conductance and concomitant, discretely collected dissolved organic carbon, dissolved inorganic carbon, and particulate carbon samples to calculate total carbon (TC) concentrations at 15-minute intervals. Calculated TC concentrations typically increased as flow was decreasing and decreased as flow was increasing. TC loads were calculated by multiplying concentrations and flow volume, and the difference between the load calculations for input/output locations of the swamp flow system was used to determine the aquatic carbon export from the study area. Calculated monthly TC loads ranged from 0 metric tons in spring 2017 at both stations to 3,145 and 7,821 metric tons in September 2017 at 022889001 and 022909471, respectively. During 2016, the annual loads were 10,479 and 15,243 metric tons at 022889001 and 022909471, respectively. Calculated monthly aquatic TC exports from the study area ranged from −0.7 gram of carbon per square meter in May 2016 to 44.1 grams of carbon per square meter during September 2017. The carbon export from the study area varied monthly, increased as flow increased, and was greatly influenced by Hurricane Irma in September 2017. The aquatic TC export from the Sweetwater Strand study area was 42.0 grams of carbon per square meter per year in 2016, which is substantially (about 15 times) larger than the estimated overall mean riverine carbon export per square meter for the eastern United States; however, it was also less than the monthly export of carbon in September 2017. The monthly aquatic carbon export from the study area in September 2017 alone was greater than the aquatic carbon export from all of 2016, which is largely the result of the substantial increase in flow attributed to Hurricane Irma.

Florida↗

USGS2020

Measured and calculated nitrate and dissolved organic carbon concentrations and loads at the W.P. Franklin Lock and Dam, S-79, south Florida, 2014-17

The U.S. Geological Survey monitored dissolved nitrate plus nitrite as nitrogen (N) and dissolved organic carbon (DOC) concentrations and calculated loads of these constituents at the W.P. Franklin Lock and Dam (S-79) from April 2014 to December 2017. Flows from Lake Okeechobee controlled by S-77, S-78 and S-79 affect water quality in the downstream Caloosahatchee River Estuary, where increased nutrients and dissolved organic matter are of concern. Numerous algal blooms have occurred in the Caloosahatchee River and downstream estuaries in recent years (2005–18) and are often attributed to eutrophication. Dissolved nitrate plus nitrite as N (hereafter, referred to as nitrate) data were collected at 15-minute intervals using a submersible ultraviolet optical nitrate sensor. The instrument data were corrected for interferences, as determined by the relation between instrument measurements and 20 concurrent laboratory values. A surrogate model, based on 36 concurrent measurements of DOC, fluorescence of chromophoric dissolved organic matter, and specific conductance, was developed to calculate DOC at 15-minute intervals. Mean and median calculated nitrate concentrations for the study period (2014–17) were both 0.21 milligram per liter (mg/L). Monthly mean nitrate concentrations ranged from 0.04 mg/L in April 2017 to 0.48 mg/L in November 2015. Monthly mean nitrate concentrations and the proportion of water that was attributed to Lake Okeechobee discharge, released through S-79, were weakly correlated and indicate that the nitrate concentrations typically decreased as the percentage of water released from the lake increased. Annual nitrate loads were 278 metric tons in 2015, 782 metric tons in 2016, and 525 metric tons in 2017. Monthly mean nitrate loads ranged from 1.2 metric tons in April 2017 to 171.3 metric tons in February 2016. Nitrate loads increased linearly with an increase in flow and typically increased during the wet season, May to October. Monthly loads of nitrate were strongly correlated with flow at S-77 and S-79. Mean and median calculated DOC concentrations for the study period were 18.3 mg/L and 18.9 mg/L, respectively. Monthly mean DOC concentrations ranged from 12.6 mg/L in May 2017 to 21.5 mg/L in September 2015. Generally, DOC concentrations were lower during the dry season months (November to April) and higher during the wet season months. Monthly mean DOC concentrations were moderately correlated with monthly mean flow volumes at S-79. There was a strong correlation between monthly mean DOC concentrations and the proportion of water released at S-79 that can be attributed directly to Lake Okeechobee, indicating that contributions between Moore Haven Lock and Dam (S-77) and S-79 have a higher DOC concentration than water released from Lake Okeechobee. Monthly mean nitrate concentrations and monthly mean DOC concentrations were strongly correlated. Annual loads of DOC were 23,960 metric tons in 2015 and 65,610 metric tons in 2016 (2014 and 2017 data were incomplete). Monthly loads of DOC ranged from 284 metric tons in May 2017 to 15,122 metric tons in September 2017, the latter corresponding to the effects from Hurricane Irma. Monthly loads of DOC were strongly correlated with flow at S-77 and S-79.

Florida↗

USGS2020

Observed and modeled mercury and dissolved organic carbon concentrations and loads at control structure S-12D, Florida Everglades, 2013–17

Mercury (Hg) has been a contaminant of concern for several decades in South Florida, particularly in the Florida Everglades. The transport and bioavailability of Hg in aquatic systems is intimately linked to dissolved organic carbon (DOC). In aquatic systems, Hg can be converted to methylmercury (MeHg), which is the form of Hg that bioaccumulates in food webs. The bioaccumulation of MeHg poses significant health risks to wildlife and humans. Fish consumption advisories triggered by elevated Hg levels first appeared in the 1980s in South Florida. Multiple structures regulate freshwater distribution to Everglades National Park, including S-12D. This report summarizes seasonal and annual concentration and load data from late September 2013 to April 2017 for the total of (1) filter-passing total mercury (FTHg), (2) filter-passing methylmercury (FMeHg), (3) particulate total mercury (PTHg), (4) particulate methylmercury (PMeHg) and, (5) DOC discharged through control structure S-12D. The loads of Hg fractions and DOC at control structure S-12D were determined by pairing discharge data with constituent concentrations estimated by empirical models based on surrogate in situ water-quality measurements. Calculated concentrations of DOC ranged from 12.8 milligrams per liter (mg/L) to 27.9 mg/L with a mean of 18.8 mg/L during the study period. Annual loads of DOC ranged from 3,950 tons in 2015 to 10,900 tons in 2016. DOC loads increased linearly with an increase in flow, and the highest monthly DOC load of 1,630 tons was observed in February 2016. Calculated concentrations of FTHg ranged from 0.35 to 1.55 nanograms per liter (ng/L) with a mean of 0.85 ng/L during the study period. Calculated concentrations of FMeHg ranged from 0.06 ng/L to 0.24 ng/L with a mean of 0.14 ng/L during the study period. Generally, FTHg and FMeHg concentrations were lower during periods of decreased flow and higher during periods of increased flow. Calculated PTHg concentrations ranged from 0.09 ng/L to 4.19 ng/L with a mean of 0.58 ng/L during the study period. Calculated PMeHg concentrations ranged from below the limit of detection <0.01 ng/L to 0.29 ng/L with a mean of 0.03 ng/L during the study period. Loads of Hg were often zero or lowest from November to May, owing to the lack of flow or low-flow conditions. FTHg and FMeHg loads increased linearly with an increase in flow and typically were highest from June to October. During periods of increasing flow or following changes in gate operations, PTHg and PMeHg constituted a greater percentage of the total Hg load. Annual loads of total Hg (filter-passing and particulate) ranged from 254 grams in 2015 to 658 grams in 2016. FTHg was the predominant contributor to the total Hg load. Information presented herein provides the first assessment of DOC and Hg loads to Everglades National Park through control structure S-12D using continuous in situ measurements of discharge and constituent surrogates and compares the surrogate model approach to loads calculated from monthly sampling. Analysis of calculated and observed loads demonstrates the significance of flow data on calculating constituent loads.

Florida↗

USGS2016

Flow characteristics and salinity patterns of tidal rivers within the northern Ten Thousand Islands, southwest Florida, water years 2007–14

Freshwater flow to the Ten Thousand Islands estuary has been altered by the construction of the Tamiami Trail and the Southern Golden Gate Estates. The Picayune Strand Restoration Project, which is associated with the Comprehensive Everglades Restoration Plan, has been implemented to improve freshwater delivery to the Ten Thousand Islands estuary by removing hundreds of miles of roads, emplacing hundreds of canal plugs, removing exotic vegetation, and constructing three pump stations. Quantifying the tributary flows and salinity patterns prior to, during, and after the restoration is essential to assessing the effectiveness of upstream restoration efforts. Tributary flow and salinity patterns during preliminary restoration efforts and prior to the installation of pump stations were analyzed to provide baseline data and preliminary analysis of changes due to restoration efforts. The study assessed streamflow and salinity data for water years 1 2007–2014 for the Faka Union River (canal flow included), East River, Little Wood River, Pumpkin River, and Blackwater River. Salinity data from the Palm River and Faka Union Boundary water-quality stations were also assessed. Faka Union River was the dominant contributor of freshwater during water years 2007–14 to the Ten Thousand Islands estuary, followed by Little Wood and East Rivers. Pumpkin River and Blackwater River were the least substantial contributors of freshwater flow. The lowest annual flow volumes, the highest annual mean salinities, and the highest percentage of salinity values greater than 35 parts per thousand (ppt) occurred in water year 2011 at all sites with available data, corresponding with the lowest annual rainfall during the study. The highest annual flow volumes and the lowest percentage of salinities greater than 35 ppt occurred in water year 2013 for all sites with available data, corresponding with the highest rainfall during the study. In water year 2014, the percentage of monitored annual flow contributed by East River increased and the percentage of flow contributed by Faka Union River decreased, compared to the earlier years. No changes in annual flow occurred at any sites west of Faka Union River. No changes in the relative flow contributions were observed during the wet season; however, the relative amounts of streamflow increased during the dry season at East River in 2014. East River had only 1 month of negative flow in 2014 compared to 6 months in 2011 and 7 months in 2008. Higher dry season flows in East River may be in response to restoration efforts. The sites to the west of Faka Union River had higher salinities on average than Faka Union River and East River. Faka Union River had the highest range in salinities, and Faka Union Boundary had the lowest range in salinities. Pumpkin River was the tributary with the lowest range in salinities. 1 Water year is defined as the 12-month period from October 1, for any given year, through September 30 of the following year.

Florida↗

USGS2016

Effects of variations in flow characteristics through W.P. Franklin Lock and Dam on downstream water quality in the Caloosahatchee River Estuary and in McIntyre Creek in the J.N. “Ding” Darling National Wildlife Refuge, southern Florida, 2010–13

The U.S. Geological Survey studied water-quality trends at the mouth of McIntyre Creek, an entry point to the J.N. “Ding” Darling National Wildlife Refuge, to investigate correlations between flow rates and volumes through the W.P. Franklin Lock and Dam and water-quality constituents inside the refuge from March 2010 to December 2013. Outflow from Lake Okeechobee, and flows from Franklin Lock, tributaries to the Caloosahatchee River Estuary, and the Cape Coral canal system were examined to determine the sources and quantity of water to the study area. Salinity, temperature, dissolved-oxygen concentration, pH, turbidity, and chromophoric dissolved organic matter fluorescence (FDOM) were measured during moving-boat surveys and at a fixed location in McIntyre Creek. Chlorophyll fluorescence was also recorded in McIntyre Creek. Water-quality surveys were completed on 20 dates between 2011 and 2014 using moving-boat surveys. Franklin Lock contributed the majority of flow to the Caloosahatchee River. Between 2010 and 2013, the monthly mean flow rate at Franklin Lock ranged from 29 cubic feet per second in May 2011 to 10,650 cubic feet per second in August 2013. Instantaneous near-surface salinity in McIntyre Creek ranged from 12.9 parts per thousand on September 26, 2013, to 37.9 parts per thousand on June 27, 2011. Salinity in McIntyre Creek decreased with increasing flow rate through Franklin Lock. Flow rates through Franklin Lock explained 61 percent of the variation in salinity in McIntyre Creek. Salinity data from moving-boat surveys also indicate that an increase in flow rate at Franklin Lock decreases salinity in the Caloosahatchee River Estuary, and a reduction or elimination in flow increases salinity. The FDOM in McIntyre Creek was positively correlated with flow at Franklin Lock, and 54 percent of the variation in FDOM can be attributed to the flow rate through Franklin Lock. Data from moving-boat surveys indicate that FDOM increases when flow volume from Franklin Lock increases. The highest FDOM recorded during a survey was at Billy’s Creek. Chlorophyll fluorescence was positively correlated with flow at Franklin Lock, with 23 percent of the variation explained by the flow rate at Franklin Lock. An increase in flow rate at Franklin Lock resulted in a decrease in pH (21 percent of variation explained by flow rates). Data from the pH surveys indicate an increase in pH with distance from Franklin Lock. Turbidity and dissolved oxygen near the surface in McIntyre Creek were not correlated with flow rate at Franklin Lock. Moving-boat surveys did not document a change in turbidity or dissolved oxygen with a change in distance from the Franklin Lock. Correlations between Franklin Lock flow rate and water quality in McIntyre Creek indicate that releases at Franklin Lock affect water quality in the Caloosahatchee River Estuary and Ding Darling Refuge.

Florida↗

USGS2014

Flow monitoring along the western Tamiami Trail between County Road 92 and State Road 29 in support of the Comprehensive Everglades Restoration Plan, 2007-2010

The construction of U.S. Highway 41 (Tamiami Trail), the Southern Golden Gate Estates development, and the Barron River Canal has altered the flow of freshwater to the Ten Thousand Islands estuary of Southwest Florida. Two restoration projects, the Picayune Strand Restoration Project and the Tamiami Trail Culverts Project, both associated with the Comprehensive Everglades Restoration Plan, were initiated to address this issue. Quantifying the flow of freshwater to the estuary is essential to assessing the effectiveness of these projects. The U.S. Geological Survey conducted a study between March 2006 and September 2010 to quantify the freshwater flowing under theTamiami Trail between County Road 92 and State Road 29 in southwest Florida, excluding the Faka Union Canal (which is monitored by South Florida Water Management District). The study period was after the completion of the Tamiami Trail Culverts Project and prior to most of the construction related to the Picayune Restoration Project. The section of the Tamiami Trail that was studied contains too many structures (35 bridges and 16 culverts) to cost-effectively measure each structure on a continuous basis, so the area was divided into seven subbasins. One bridge within each of the subbasins was instrumented with an acoustic Doppler velocity meter. The index velocity method was used to compute discharge at the seven instrumented bridges. Periodic discharge measurements were made at all structures, using acoustic Doppler current profilers at bridges and acoustic Doppler velocity meters at culverts. Continuous daily mean values of discharge for the uninstrumented structures were calculated on the basis of relations between the measured discharge at the uninstrumented stations and the discharge and stage at the instrumented bridge. Estimates of daily mean discharge are available beginning in 2006 or 2007 through September 2010 for all structures. Subbasin comparison is limited to water years 2008–2010. The Faka Union Canal contributed more than half (on average 60 percent) of the flow under the Tamiami Trail between State Road 29 and County Road 92 during water years 2008–2010. During water years 2008–2010, an average 9 percent of the flow through the study area came from west of the Faka Union Canal and an average 31 percent came from east of the Faka Union Canal. Flow data provided by this study serve as baseline information about the seasonal and spatial distribution of freshwater flow under the Tamiami Trail between County Road 92 and State Road 29, and study results provide data to evaluate restoration efforts.

Florida↗