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Geology topics

Alissa L. Coes

Publications and source records attributed to Alissa L. Coes.

16 recordsLinked to original sources

Estimation of dissolved-solids concentrations using continuous water-quality monitoring and regression models at four sites in the Yuma area, Arizona and California, January 2017 through March 2019

Multiple linear regression models were developed to estimate dissolved-solids concentrations in water at four sites in the Yuma area between Imperial Dam, Arizona and California and the southerly international boundary with Mexico at San Luis, Arizona. Continuous and discrete water-quality data were collected at gaging stations in the Colorado River upstream from Imperial Dam, Arizona-California, the Colorado River below Cooper wasteway near Yuma, Arizona, the Yuma Main Drain above Arizona–Sonora, Mexico boundary, and the 242 lateral above Main Drain at the Arizona–Sonora boundary. Continuous specific conductance and water temperature data were collected at each site between January 2017 and March 2019. Bi-weekly to monthly dissolved-solids water samples were collected during the same period. Continuous specific conductance data collected at the Colorado River below Cooper wasteway were affected by poorly mixed streamflow during periods when the Pilot Knob Hydro-electric Plant was releasing water to the river. The continuous specific conductance data for the site downstream from Cooper wasteway were corrected using mean specific conductance values computed from cross-section measurements collected during site visits. Continuous specific conductance data were affected by sensor fouling issues at the 242 lateral site, and continued operation at the site would require more frequent visits for cleaning and service to ensure data quality. During the study, instream specific conductance readings ranged from 966 to 3,030 microsiemens per centimeter (μS/cm) at 25 degrees Celsius. Computed dissolved-solids concentrations from discrete samples ranged from 690 to 2,580 milligrams per liter (mg/L). Dissolved-solids concentrations were estimated from regression models using the optimal relation between dissolved solids and environmental factors, such as specific conductance, water temperature, dissolved oxygen, streamflow, and seasonality. Specific conductance was the primary factor at all four sites and explained 87.6 to 94 percent of variation in dissolved solids. Water temperature, as an indicator of seasonality, was determined to be a statistically significant secondary factor at both the Colorado River above Imperial Dam and Colorado River below Cooper wasteway sites explaining an additional 6.9 and 2.1 percent of variation in dissolved solids, respectively. Regression models explained 87.6 to 96.9 percent of the variation in dissolved solids; the root mean square error in the modeled data ranged between about 6 and 27 mg/L.

Arizona, California

Spatial and temporal distribution of bacterial indicators and microbial-source tracking within Tumacácori National Historical Park and the upper Santa Cruz River, southern Arizona and northern Mexico, 2015–2016

Tumacácori National Historical Park (TUMA) in southern Arizona protects the culturally important Mission San José de Tumacácori, while also managing a part of the ecologically diverse riparian corridor of the Santa Cruz River. The quality of the water flowing through depends solely on upstream watershed activities, and among the water-quality issues concerning TUMA is the microbiological pathogens in the river introduced by human and animal sources that pose a significant human health risk to employees and visitors. The U.S. Geological Survey (USGS) conducted a 3-year study to understand the sources, timing, and distribution of the fecal-indicator bacteria Escherichia coli ( E. coli ) within TUMA and the upstream watershed. The information provided in this investigation is a result of a comprehensive approach to quantify the spatial and temporal variability of E. coli and suspended sediment in the Upper Santa Cruz River Watershed. Several types of flow were sampled from base flow to flood flow and at high frequency intervals (rise, peak, and recession) to determine daily variability, as well as seasonal variability. Hydrologic data collection and estimation techniques were used to establish a hydrologic relation with E. coli and suspended sediment. Furthermore, source tracking was used to describe the potential sources of E. coli . Models were developed that are expected to be useful for predicting E. coli concentrations to help TUMA managers understand instantaneous conditions to keep the public and staff informed about potentially harmful water-quality conditions. In addition, the concentration, flux, and source information will provide more accurate data for other surface-water modeling and can be useful in the development of total maximum daily load standards. This will help TUMA describe the water-quality conditions at the park and waters flowing through the park, as well as prioritize and help carry out future best-management actions to address these issues.

Tumacácori National Historical Park, Upper Santa C

Assessment of polycyclic aromatic hydrocarbon concentrations in southern Lake Powell, Glen Canyon National Recreation Area, Arizona and Utah, 2016–17

Polycyclic aromatic hydrocarbon contamination related to boat use is one of the most important water-quality issues affecting Lake Powell. High concentrations of polycyclic aromatic hydrocarbons in water are common around marinas and other areas with extensive motorboat activity because of releases of uncombusted or partially combusted oil and gasoline from boat engines. The fate of these compounds in Lake Powell is of serious environmental concern because of their toxicity and carcinogenicity and their moderate persistence once they enter the aquatic ecosystem. In 2016–17, the U.S. Geological Survey (USGS) assessed the presence and concentrations of polycyclic aromatic hydrocarbons in Lake Powell at seven sites where concentrations have historically been elevated and one site where concentrations have historically been relatively low. Semipermeable membrane devices were used to collect samples that represent time-weighted averages of polycyclic aromatic hydrocarbon concentrations in water over one-month deployment periods. Samples were collected from the epilimnion of the lake at each of the eight sampling sites during two periods of relatively high boat use (summer), and one period of relatively low boat use (spring). Twenty-eight out of 33 polycyclic aromatic hydrocarbons analyzed were detected in Lake Powell during the three sampling events. During the two summer sampling events, concentrations were generally higher, and more compounds were detected, than during the spring sampling event. Twenty-two of the polycyclic aromatic hydrocarbons analyzed in 2016–17 had previously been analyzed by the USGS in the summer of 2010 at the same 8 sites using the same collection method. Eleven of 22 compounds were detected in the summer 2010, summer 2016, and summer 2017 sampling events, and 1 was detected in the summer 2010 and summer 2017 samplings, but not in the summer 2016 sampling event. During both the current and previous sampling events, concentrations were generally higher, and more compounds were detected, at the high-use marina sites located most downstream on the lake. The consistent presence of a wide range of polycyclic aromatic hydrocarbons in the water of Lake Powell indicates chronic and (or) recent anthropogenic sources of contamination. The results from this study will provide the National Park Service with information necessary to determine if the current regulations on emission standards for personal watercraft used on Lake Powell are effective in lowering polycyclic aromatic hydrocarbon concentrations in the lake.

Arizona, Utah

Investigation of recent decadal-scale cyclical fluctuations in salinity in the lower Colorado river

Beginning in the late 1970s, 10- to 15-year cyclical oscillations in salinity were observed at lower Colorado River monitoring sites, moving upstream from the international border with Mexico, above Imperial Dam, below Hoover Dam, and at Lees Ferry. The cause of these cyclical trends in salinity was unknown. These salinity cycles complicate the U.S. Bureau of Reclamation's (Reclamation) responsibility for managing salinity in the river for delivery of water to Mexico to meet treaty obligations. This study develops a conceptual model of the salinity cycles from time-series water quality, streamflow, and precipitation data in both the lower and upper Colorado River Basins in order to provide Reclamation the ability to understand, anticipate, and manage future salinity cycles in the lower river. Compared with the Lees Ferry record, both maximum and minimum salinity levels increase downstream by about 25% at Hoover Dam, by about 49% at Imperial Dam, and by about 69% at the northern international boundary with Mexico. In the upper basin, cyclical salinity trends are evident at the outflow of three major tributaries, where salinity is also noted to be inversely related to streamflow. Time series trends in precipitation within the catchments of the three upper basin tributaries indicate cyclical periods with above normal precipitation and periods with below normal precipitation. Periods of greater than normal precipitation in the contributing areas correspond with declines in salinity at the catchment monitoring sites and periods of less than normal precipitation correspond with rising salinity at the sites. Based on the conceptual model developed in this investigation, a multiple linear regression model was developed using a stepwise variable selection procedure to simulate salinity in Lake Powell inflow. Important variables in the explanation of salinity entering Lake Powell include flow from the three upper basin tributaries, seasonality, and mean precipitation in the upper basin, among others. The root mean square error of prediction for the MLR model was 31.48 mg/L (5.7%).

Arizona, Colorado, Nevada, New Mexico, Utah, Wyomi

Conceptual and numerical models of dissolved solids in the Colorado River, Hoover Dam to Imperial Dam, and Parker Dam to Imperial Dam, Arizona, California, and Nevada

Conceptual and numerical models were developed to understand and simulate monthly flow-weighted dissolved-solids concentrations in the Colorado River at Imperial Dam. The ability to simulate dissolved-solids concentrations at this location will help the Bureau of Reclamation satisfy the binational agreement on the volume and salinity of Colorado River water delivered to Mexico. A robust spatial- and temporal-resolution dataset that consists of river discharge and dissolved-solids concentration and load information between January 1990 and September 2016 for 10 sites on canals, drains, tributaries, and the main stem of the Colorado River between Hoover and Imperial Dams was generated. Daily mean dissolved-solids concentrations were estimated and monthly mean dissolved-solids loads were computed for each site. Spatial and temporal load patterns, and historical and current controls on loads and concentrations, were analyzed in order to develop a conceptual model of dissolved-solids transport between Hoover and Imperial Dams. Two numerical models describing the relations between dissolved-solids concentrations and components controlling dissolved-solids concentrations and loads were developed, calibrated, and verified. Between January 1990 and September 2016, there was a 98.8-million-acre-feet loss of water and a 57.0-million-ton loss of dissolved-solids load from the Colorado River between Hoover and Imperial Dams. Between Hoover and Parker Dams, about 69.0 million acre-feet of water was lost and 51.1 million tons of dissolved solids were lost; between Parker and Imperial Dams, about 29.8 million acre-feet of water was lost and 5.9 million tons of dissolved solids were lost. Water was removed from the river at a relatively consistent rate over the 25-year study period through water transfers to California and Arizona, evapotranspiration from crop irrigation, transpiration processes of riparian vegetation, and evaporation from the river main stem. Dissolved solids were removed from the river between Hoover and Parker Dams at a relatively constant rate through water transfers to California and Arizona, and water pumped from the river for irrigation within the Mohave Valley. A small amount of dissolved solids are gained by the river from inflow from the Bill Williams River. Between Parker and Imperial Dams, however, dissolved solids were not removed from the river at a consistent rate over the study period. Dissolved solids were generally removed from the river from 1990 to 2012, then gained by the river from 2012 to 2015, and then removed from the river from 2015 through 2016. Dissolved solids are assumed to be removed from the river and accumulated within the floodplain sediments and aquifers during irrigation processes; some dissolved solids may also be removed from the river through uptake by crops and riparian vegetation. Dissolved solids accumulated on the landscape and in the floodplain aquifer during irrigation are transported to the river during periods when the hydraulic gradient between the floodplain aquifer and the river is increased, causing a gain in dissolved solids in the river. Dissolved-solids gains in the river occur during periods of relatively low river discharge, such as during the winter months and during drier climatic conditions. Two numerical models were developed and coefficients were estimated by using data from a May 2008-September 2016 calibration period. One model simulates concentrations at Imperial Dam based on the Colorado River system downstream from Parker Dam, and the other model simulates concentrations at Imperial Dam based on the Colorado River system downstream from Hoover Dam. Both models simulated monthly flow-weighted concentrations of dissolved solids for the Colorado River at Imperial Dam, which corresponded well with observed concentrations for the entire study period. The models are more sensitive to input variables of monthly discharge of the Colorado River below Parker Dam and monthly flow-weighted dissolved-solids concentrations of the Colorado River below Hoover Dam and Parker Dam than to the rate of change in concentration with respect to time and the combined discharge of the Colorado River Indian Reservation Main Canal and the Palo Verde Canal. The calibrated models can be used to run scenarios of future monthly flow-weighted dissolved-solids concentrations in the Colorado River at Imperial Dam. Although the models are expected to provide concentration estimates within 18 milligrams per liter (Parker Dam to Imperial Dam model) to 22 milligrams per liter (Hoover Dam to Imperial Dam model), 95 percent of the time, the error of future scenarios increases as uncertainty in the estimated future input variables increases.

Arizona, California, Nevada

Collection methods and quality assessment for Escherichia coli, water quality, and microbial source tracking data within Tumacácori National Historical Park and the upper Santa Cruz River, Arizona, 2015-16

Tumacácori National Historical Park protects the culturally important Mission, San José de Tumacácori, while also managing a portion of the ecologically diverse riparian corridor of the Santa Cruz River. This report describes the methods and quality assurance procedures used in the collection of water samples for the analysis of Escherichia coli ( E. coli ), microbial source tracking markers, suspended sediment, water-quality parameters, turbidity, and the data collection for discharge and stage; the process for data review and approval is also described. Finally, this report provides a quantitative assessment of the quality of the E. coli , microbial source tracking, and suspended sediment data. The data-quality assessment revealed that bias attributed to field and laboratory contamination was minimal, with E. coli detections in only 3 out of 33 field blank samples analyzed. Concentrations in the field blanks were several orders of magnitude lower than environmental concentrations. The microbial source tracking (MST) field blank was below the detection limit for all MST markers analyzed. Laboratory blanks for E. coli at the USGS Arizona Water Science Center and laboratory blanks for MST markers at the USGS Ohio Water Microbiology Laboratory were all below the detection limit. Irreplicate data for E. coli and suspended sediment indicated that bias was not introduced to the data by combining samples collected using discrete sampling methods with samples collected using automatic sampling methods. The split and sequential E. coli replicate data showed consistent analytical variability and a single equation was developed to explain the variability of E. coli concentrations. An additional analysis of analytical variability for E. coli indicated analytical variability around 18 percent relative standard deviation and no trend was observed in the concentration during the processing and analysis of multiple split-replicates. Two replicate samples were collected for MST and individual markers were compared for a base flow and flood sample. For the markers found in common between the two types of samples, the relative standard deviation for the base flow sample was more than 3 times greater than the markers in the flood sample. Sequential suspended sediment replicates had a relative standard deviation of about 1.3 percent, indicating that environmental and analytical variability was minimal. A holding time review and laboratory study analysis supported the extended holding times required for this investigation. Most concentrations for flood and base-flow samples were within the theoretical variability specified in the most probable number approach suggesting that extended hold times did not overly influence the final concentrations reported.

Arizona

Characterization of the quality of water, bed sediment, and fish in Mittry Lake, Arizona, 2014–15

Water, bed-sediment, and fish sampling was conducted in Mittry Lake, Arizona, in 2014–15 to establish current water-quality conditions of the lake. The parameters of temperature, dissolved-oxygen concentration, specific conductance, and alkalinity were measured in the field. Water samples were collected and analyzed for dissolved major ions, dissolved trace elements, dissolved nutrients, dissolved organic carbon, dissolved pesticides, bacteria, and suspended-sediment concentrations. Bed-sediment and fish samples were analyzed for trace elements, halogenated compounds, total mercury, and methylmercury. U.S. Environmental Protection Agency secondary maximum contaminant levels in drinking water were exceeded for sulfate, chloride, and manganese in the water samples. Trace-element concentrations were relatively similar between the inlet, middle, and outlet locations. Concentrations for nutrients in all water samples were below the Arizona Department of Environmental Quality’s water-quality standards for aquatic and wildlife uses, and all bacteria levels were below the Arizona Department of Environmental Quality’s recommended recreational water-quality criteria. Three out of 81 pesticides were detected in the water samples. Trace-element concentrations in bed sediment were relatively consistent between the inlet, middle, and outlet locations. Lead, manganese, nickel, and zinc concentrations, however, decreased from the inlet to outlet locations. Concentrations for lead, nickel, and zinc in some bed-sediment samples exceeded consensus-based sediment-quality guidelines probable effect concentrations. Eleven out of 61 halogenated compounds were detected in bed sediment at the inlet location, whereas three were detected at the middle location, and five were detected at the outlet location. No methylmercury was detected in bed sediment. Total mercury was detected in bed sediment at concentrations below the consensus-based sediment-quality guidelines probable effect concentration. Sixteen trace elements were detected in at least one of the fish-tissue samples, and trace-element concentrations were relatively consistent between the three fish-tissue samples. Seven halogenated compounds were detected in at least one of the whole-body fish samples; four to five compounds were detected in each fish. One fish-tissue sample exceeded the U.S. Environmental Protection Agency human health consumption criteria for methylmercury.

Texas

Hydrogeology, hydrologic effects of development, and simulation of groundwater flow in the Borrego Valley, San Diego County, California

Executive Summary The Borrego Valley is a small valley (110 square miles) in the northeastern part of San Diego County, California. Although the valley is about 60 miles northeast of city of San Diego, it is separated from the Pacific Ocean coast by the mountains to the west and is mostly within the boundaries of Anza-Borrego Desert State Park. From the time the basin was first settled, groundwater has been the only source of water to the valley. Groundwater is used for agricultural, recreational, and municipal purposes. Over time, groundwater withdrawal through pumping has exceeded the amount of water that has been replenished, causing groundwater-level declines of more than 100 feet in some parts of the basin. Continued pumping has resulted in an increase in pumping lifts, reduced well efficiency, dry wells, changes in water quality, and loss of natural groundwater discharge. As a result, the U.S. Geological Survey began a cooperative study of the Borrego Valley with the Borrego Water District (BWD) in 2009. The purpose of the study was to develop a greater understanding of the hydrogeology of the Borrego Valley Groundwater Basin (BVGB) and to provide tools to help evaluate the potential hydrologic effects of future development. The objectives of the study were to (1) improve the understanding of groundwater conditions and land subsidence, (2) incorporate this improved understanding into a model that would assist in the management of the groundwater resources in the Borrego Valley, and (3) use this model to test several management scenarios. This model provides the capability for the BWD and regional stakeholders to quantify the relative benefits of various options for increasing groundwater storage. The study focuses on the period 1945–2010, with scenarios 50 years into the future. This report documents and presents (1) an analysis of the conceptual model, (2) a description of the hydrologic features, (3) a compilation and analysis of water-quality data, (4) the measurement and analysis of land subsidence by using geophysical and remote sensing techniques, (5) the development and calibration of a two-dimensional borehole-groundwater-flow model to estimate aquifer hydraulic conductivities, (6) the development and calibration of a three-dimensional (3-D) integrated hydrologic flow model, (7) a water-availability analysis with respect to current climate variability and land use, and (8) potential future management scenarios. The integrated hydrologic model, referred to here as the “Borrego Valley Hydrologic Model” (BVHM), is a tool that can provide results with the accuracy needed for making water-management decisions, although potential future refinements and enhancements could further improve the level of spatial and temporal resolution and model accuracy. Because the model incorporates time-varying inflows and outflows, this tool can be used to evaluate the effects of temporal changes in recharge and pumping and to compare the relative effects of different water-management scenarios on the aquifer system. Overall, the development of the hydrogeologic and hydrologic models, data networks, and hydrologic analysis provides a basis for assessing surface and groundwater availability and potential water-resource management guidelines.

California

Initial characterization of the groundwater system near the Lower Colorado Water Supply Project, Imperial Valley, California

In 2009, the U.S. Geological Survey, in cooperation with the city of Needles, began a study of the hydrogeology along the All-American Canal, which conveys water from the Colorado River to the Imperial Valley. The focus of this study was to gain a better understanding of the effect of lining the All-American Canal, and other management actions, on future total dissolved solids concentrations in groundwater pumped by Lower Colorado Water Supply Project wells that is delivered to the All-American Canal. The study included the compilation and evaluation of previously published hydrogeologic and geochemical information, establishment of a groundwater-elevation and groundwater-quality monitoring network, results of monitoring groundwater elevations and groundwater quality from 2009 to 2011, site-specific hydrologic investigations of the Lower Colorado Water Supply Project area, examination of groundwater salinity by depth by using time-domain electromagnetic surveys, and monitoring of groundwater-storage change by using microgravity methods. Prior to the completion of the All-American Canal in 1940, groundwater in the study area flowed from east to west, and groundwater was recharged primarily by underflow from the Colorado River Valley. After construction of the All-American Canal, groundwater elevations were altered in the study area as seepage of Colorado River water from the All-American Canal and other canals became the dominant recharge source. By 2005, groundwater elevations had increased by as much as 50–70 feet along the All-American Canal. Superimposed on the east-to-west groundwater gradient was groundwater movement away from the All-American Canal to the north and, most likely, to the south into Mexico. After lining the All-American Canal, from 2007 to 2010, groundwater elevations declined as seepage from the All-American Canal decreased. Between 2005 (the last complete groundwater-elevation survey prior to lining the All-American Canal) and 2011, groundwater elevations declined 20–40 feet along the All-American Canal and as much as 40–45 feet in the vicinity of Lower Colorado Water Supply Project pumping wells. Water-quality and isotope data were used to differentiate historically recharged groundwater from groundwater more recently recharged by seepage of Colorado River surface water from the All-American Canal. Prior to the completion of the All-American Canal in 1940, groundwater in the southern part of the study area was primarily sodium-chloride/sulfate type water that had relatively low total dissolved solids concentrations (500–820 milligrams per liter). During 2007–11, groundwater in the southern part of the study area, near the All-American Canal, ranged from sodium-chloride type water to mixed-cation-sulfate type water that had total dissolved solids concentrations generally less than 879 milligrams per liter. The stable-isotopic signature of groundwater near the All-American Canal sampled in 2009–11 indicated inputs of Colorado River water that had been affected by evaporation, and radioactive isotopes indicated that a substantial fraction of water had been recharged recently, within the past 60 years. This contrasted with historically recharged groundwater near the All-American Canal, which had higher sodium and chloride concentrations, and lower calcium and sulfate concentrations, than recent recharge from the All-American Canal. Groundwater at a distance from the All-American Canal, in the East Mesa, Algodones Dunes, Pilot Knob Mesa, and Cargo Muchacho Mountains piedmont, was found to have higher total dissolved solids concentrations (generally greater than 1,000 milligrams per liter) than recently recharged groundwater near the All-American Canal. Time-domain electromagnetic data indicated that low-salinity groundwater was present down to about 377 feet below land surface near the All-American Canal; groundwater salinity at depth increased with distance north from the All-American Canal. Groundwater several miles or more from the canal also did not contain tritium and had a residence time on the order of thousands to tens of thousands of years. The groundwater in the piedmont of the Cargo Muchacho Mountains had a distinctly light stable-isotopic signature indicative of recharge by runoff from local precipitation, whereas the stable isotopic signature of groundwater in the East Mesa and the Algodones Dunes indicated a mixture of local precipitation and historic Colorado River recharge sources. During and after lining the All-American Canal (2007–11), groundwater elevations in the Lower Colorado Water Supply Project area declined, while total dissolved solids concentrations remained relatively constant. The total dissolved solids concentrations in well LCWSP-2 ranged from 650 to 800 milligrams per liter during this study. Depth-specific water-quality and isotope sampling at well LCWSP-2 indicated the groundwater pumped from the deeper part of the screened interval (240–280 feet below land surface) contained a greater proportion of historical groundwater than the groundwater pumped from the shallower part of the screened interval (350–385 feet below land surface). Age-tracer data at well LCWSP-2 indicated that all depths of the screened interval had received recent recharge from seepage of Colorado River water from the All-American Canal.

California

Sampling trace organic compounds in water: a comparison of a continuous active sampler to continuous passive and discrete sampling methods

A continuous active sampling method was compared to continuous passive and discrete sampling methods for the sampling of trace organic compounds (TOCs) in water. Results from each method are compared and contrasted in order to provide information for future investigators to use while selecting appropriate sampling methods for their research. The continuous low-level aquatic monitoring (CLAM) sampler (C.I.Agent® Storm-Water Solutions) is a submersible, low flow-rate sampler, that continuously draws water through solid-phase extraction media. CLAM samplers were deployed at two wastewater-dominated stream field sites in conjunction with the deployment of polar organic chemical integrative samplers (POCIS) and the collection of discrete (grab) water samples. All samples were analyzed for a suite of 69 TOCs. The CLAM and POCIS samples represent time-integrated samples that accumulate the TOCs present in the water over the deployment period (19–23 h for CLAM and 29 days for POCIS); the discrete samples represent only the TOCs present in the water at the time and place of sampling. Non-metric multi-dimensional scaling and cluster analysis were used to examine patterns in both TOC detections and relative concentrations between the three sampling methods. A greater number of TOCs were detected in the CLAM samples than in corresponding discrete and POCIS samples, but TOC concentrations in the CLAM samples were significantly lower than in the discrete and (or) POCIS samples. Thirteen TOCs of varying polarity were detected by all of the three methods. TOC detections and concentrations obtained by the three sampling methods, however, are dependent on multiple factors. This study found that stream discharge, constituent loading, and compound type all affected TOC concentrations detected by each method. In addition, TOC detections and concentrations were affected by the reporting limits, bias, recovery, and performance of each method.

Science of the Total Environment

Groundwater availability in the Atlantic Coastal Plain of North and South Carolina

The Atlantic Coastal Plain aquifers and confining units of North and South Carolina are composed of crystalline carbonate rocks, sand, clay, silt, and gravel and contain large volumes of high-quality groundwater. The aquifers have a long history of use dating back to the earliest days of European settlement in the late 1600s. Although extensive areas of some of the aquifers have or currently (2009) are areas of groundwater level declines from large-scale, concentrated pumping centers, large areas of the Atlantic Coastal Plain contain substantial quantities of high-quality groundwater that currently (2009) are unused. Groundwater use from the Atlantic Coastal Plain aquifers in North Carolina and South Carolina has increased during the past 60 years as the population has increased along with demands for municipal, industrial, and agricultural water needs. While North Carolina and South Carolina work to increase development of water supplies in response to the rapid growth in these coastal populations, both States recognize that they are facing a number of unanswered questions regarding availability of groundwater supplies and the best methods to manage these important supplies. An in-depth assessment of groundwater availability of the Atlantic Coastal Plain aquifers of North and South Carolina has been completed by the U.S. Geological Survey Groundwater Resources Program. This assessment includes (1) a determination of the present status of the Atlantic Coastal Plain groundwater resources; (2) an explanation for how these resources have changed over time; and (3) development of tools to assess the system's response to stresses from potential future climate variability. Results from numerous previous investigations of the Atlantic Coastal Plain by Federal and State agencies have been incorporated into this effort. The primary products of this effort are (1) comprehensive hydrologic datasets such as groundwater levels, groundwater use, and aquifer properties; (2) a revised hydrogeologic framework; (3) simulated water budgets of the overall study area along with several subareas; and (4) construction and calibration of a numerical modeling tool that is used to forecast the potential effects of climate change on groundwater levels.

North Carolina, South Carolina

Water quality in the central Arizona basins, Arizona, 1995-98

The water quality in rivers and streams and in selected aquifers in central Arizona basins in Arizona is described and illustrated. Major ions, nitrogen and other nutrients, and pesticides and some of their breakdown compounds were analyzed in both surface and ground water. Biological communities that included fish, invertebrates, and algae, were described in relation to stream water quality. Volatile organic compounds that originate from fuels, solvents, and industry were analyzed from ground-water samples. Agricultural and urban land-use effects on shallow ground water are compared and contrasted.

Circular

Hydrogeologic investigations of the Sierra Vista subwatershed of the Upper San Pedro Basin, Cochise County, southeast Arizona

The hydrogeologic system in the Sierra Vista subwatershed of the Upper San Pedro Basin in southeastern Arizona was investigated for the purpose of developing a better understanding of stream-aquifer interactions. The San Pedro River is an intermittent stream that supports a narrow corridor of riparian vegetation. Withdrawal of ground water will result in reduced discharge from the basin through reduced base flow and evapotranspiration; however, the rate and location of reduced discharge are uncertain. The investigation resulted in better definition of distributions of silt and clay in the regional aquifer; changes in seasonal precipitation, runoff, and base flow in the San Pedro River; sources of base flow; and regional water-level changes. Regional ground-water flow is separated into deep-confined and shallow-unconfined systems by silt and clay. Precipitation, runoff, and base flow declined at the Charleston streamflow-gaging station from 1936 through 1997 for the months of June through October. Base flow at the Charleston station during 1996 and 1997 was primarily supplied by ground water recharged near the San Pedro River during recent major runoff and by minor contributions from the regional aquifer. The decline in base flow, about 2 cubic feet per second, has several probable causes including declining runoff and recharge near the river during June through October and increased interception of ground-water flow to the river by wells and phreatophytes. Water levels in wells throughout the regional aquifer generally declined at rates of 0.2 to 0.5 feet per year between 1940 and the mid-1980's, which corresponded with a period of below-average winter precipitation. Water levels in wells in the Fort Huachuca and Sierra Vista areas declined at rates that were faster than regional rates of decline through 1998 and caused diversion of ground-water flow that would have discharged along perennial stream reaches.

Arizona