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Geology topics

A.K. Vuletich

Publications and source records attributed to A.K. Vuletich.

8 recordsLinked to original sources

A dolomitized shelfedge hardground in the northern Gulf of Mexico

An elongated calcareous hardground occurs on the shelfedge northeast of the Mississippi Trough. High-resolution seismic reflection profiles show that the hardground is in 90-110 m of water, is 70-250 m wide, at least 2.3 km long, and of low relief (5-10 m). The hardground is composed of dolostone and coquinoid limestone, and exhibits a dead biofacies of nodular and encrusting calcium carbonate-secreting organisms that are significantly different from those forms living in the adjacent unconsolidated sediments. Cementation of the hardground substrate by primary dolomite was initiated during early diagenesis close to the sea floor and progressed by concretionary growth under an interstitial environment partially open to marine molecular fluxes. The bicarbonate necessary to form the dolomite came from an admixture of isotopically light thermogenic and sedimentary organic carbon sources and an isotopically heavier marine source. Exposed surfaces of the dolostone, which have been heavily bioeroded, are covered by an oxidized, goethite-rich, reddish-brown rind. The coquina is primarily composed of whole and fragmented mollusk shells and was deposited in a higher-energy environment than the precursor sediments of the dolostone. The hardground was preserved during the Holocene transgression because of its lithified nature and the top has been intermittently swept free of finer detritus by current action.

Alabama, Florida, Louisiana, Mississippi, Texas

Character, origin and occurrence of natural gases in the Anadarko basin, southwestern Kansas, western Oklahoma and Texas Panhandle, U.S.A.

Natural gas production in the Anadarko basin comes from three geographically separated areas that can be differentiated by age of reservoir and by inferred nature of organic, thermal origin of the gases. In the central basin, non-associated gases are produced mainly from Upper Mississippian and Pennsylvanian sandstones. Gas samples are from reservoirs as much as 6588 m deep. Gases become isotopically heavier (??13C1-values range from -49.8 to -33.2???) and chemically drier (C2+-values range from 1-33%) with increasing level of thermal maturity. Gases were generated mainly from interbedded shales with type-III kerogen during the mature and post-mature stages of hydrocarbon generation. Deviations from the trend are due to vertical migration and mixing of gases generated at different levels of thermal maturity over the past 250 Myr. In the giant Panhandle-Hugoton field, non-associated gases are generally produced from Permian carbonates at depths of <900 m. Gases display little compositional variation (mean ??13C1-value is -43.2???, mean C2+-value is 14%). Because organic-rich, mature source rocks are not present in the area, gases probably were generated in the central basin from Pennsylvanian or older source rocks during the mature stage of hydrocarbon generation. This interpretation implies migration over distances as much as several hundred kilometers. In the Sooner Trend, associated gases are produced from Silurian, Devonian and Mississippian carbonates at depths as great as 2950 m and were generated from type-II kerogen during the mature stage of hydrocarbon generation. Associated oil usually correlates with extracts of the Upper Devonian and Lower Mississippian Woodford Shale. Gases are isotopically lighter (mean ??13C1-value is -43.9???) and chemically wetter (mean C2+ value is 14%) than those derived from type-III kerogen at an equivalent level of thermal maturity. ?? 1988.

Chemical Geology

Isotopic composition of interstitial fluids in sediment of the Nankai Trough, Deep Sea Drilling Project Leg 87

The isotopic compositions of dissolved CO2 and CH4 in sediments of the Nankai Trough indicate that CH4 is formed during early diagenesis by microbial reduction of CO2 . At the shallowest sampled depths, the CO2 dissolved in the pore water is unusually enriched in 12C (δ13C = - 35.2‰), indicating contribution of CO2 from oxidation of CH4 . The most intense microbiological activity appears to be confined to the uppermost 50 m of sediment, based on relative lack of change in the isotopic compositions below this depth. Gas hydrate probably is not present at these localities (Sites 582, 583) because of CH4 concentrations that are insufficient to saturate the pore water with respect to gas hy drate stability

Initial Reports of the D.S.D.P.

Preliminary results of organic geochemical and stable isotope analyses of Newark supergroup rocks in the Hartford and Newark basins, Eastern U.S.

Preliminary stage-discharge relations (limit curves) have been defined for Aliceville Lock and Dam covering the period February 1980 to May 1983 (Nelson and Ming, 1983). Subsequent data collected at the dam indicates a need for a revision to the preliminary curves. Due to channel instability in the vicinity, periodic review and possible update will be needed to keep the curves current. Using 48 data points defined by the flood of December 1983, the curves have been updated and are shown in this 1985 report. (USGS)

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