USGS Science⌕ Search

Geology topics

A. K. O’Brien

Publications and source records attributed to A. K. O’Brien.

5 recordsLinked to original sources
USGS2007

Presence and distribution of trace elements in new jersey streambed sediments

ABSTRACT: The distribution of trace elements in New Jersey streambed sediments is described with respect to physiographic provinces and major drainage areas. Samples were collected during 1976–1993 at 295 sites distributed throughout New Jersey. Copper, chromium, lead, and zinc were detected with the greatest frequency and at the highest concentrations of the elements. Concentrations of most trace elements were significantly higher in streambed sediments from the New England (glaciated) and Piedmont physiographic provinces - the provinces with the lowest and highest percentages of urban land use, respectively - than in sediments from the other provinces. High trace-element concentrations in the New England (glaciated) province reflect previous mining of extensive magnetite deposits, whereas those in the Piedmont province most likely reflect urban land use. Significantly lower trace-element concentrations in streambed sediments from the Coastal Plain are attributable to the low pH of the streamwater, the lack of iron and manganese available to form coatings that scavenge trace elements, and the relatively low percentage of urban land use in the province. Trace-element concentrations were related to land use, population, or point sources in the drainage basin specific to the sampling location by using logistic regression. Results of this analysis indicate a relation between arsenic and agricultural land use; chromium and physiographic province; and copper, lead, and zinc and population density.

Journal of the American Water Resources Associatio↗
USGS2006

Interactions between groundwater and surface water in a Virginia coastal plain watershed. 2. Acid-base chemistry

A field study of surface water and groundwater interactions during baseflow and stormflow conditions was performed at the Reedy Creek watershed in the Virginia Coastal Plain. Three estimates of the average saturated hydraulic conductivity ( K s ) of the unconfined aquifer were in reasonable agreement (ranging from 0.0033 to 0.010 cm/s), indicating that baseflow in the creek is entirely from the drainage of shallow groundwater from the relatively thin (1–6 m thick) unconfined aquifer. This relatively permeable surficial aquifer was found to be underlain by dark, olive grey, clay-silt and diatomaceous Miocene deposits of low permeability known as the Calvert Formation, which is believed to function as a confining bed in the area. A chemical hydrograph separation technique was used to resolve the contributions of [old] (pre-event) and [new] (event) water to stormflow. Results from a major rainstorm indicated that old water dominated the stormflow response of the watershed, although the new water contribution approached 40% at the hydrograph peak. Stormflow at Reedy Creek appears to result from saturation overland flow from variable source areas which include the stream channels and a significant part of the riparian wetland area. This response appears to be attributable to the transient dynamics of the shallow groundwater flow system and to the formation of localized groundwater mounds which raise the water-table to the wetland surface.

Hydrological Processes↗
USGS1996

Episodic acidification of a coastal plain stream in Virginia

This study investigates the episodic acidification of Reedy Creek, a wetland-influenced coastal plain stream near Richmond, Virginia. Primary objectives of the study were to quantify the episodic variability of acid- base chemistry in Reedy Creek, to examine the seasonal variability in episodic response and to explain the hydrological and geochemical factors that contribute to episodic acidification. Chemical response was similar in each of the seven storms examined, however, the ranges in concentrations observed were commonly greater in summer/fall storms than in winter/spring storms. An increase in SO4/2- concentration with discharge was observed during all storms and peak concentration occurred at or near peak flow. Small increases in Mg2+, Ca2+, K+ concentrations and dissolved organic carbon (DOC) were observed during most storms. At the same time, ANC, Na+ and Cl- concentrations usually decreased with increasing discharge. In summer/fall storms, the absolute increase in SO4/2- concentration was one-third to 15 times the increase observed in winter/spring storms; the decrease in ANC during summer/fall storms was usually within the range of the decrease observed in winter/spring storms. In contrast, the decrease in Na+ and Cl- concentrations during winter/spring storms was much greater than that observed during summer/fall storms. Data show that while base flow anion deficit was higher in summer/fall than in winter/spring, anion deficit decreased during most summer/fall storms. In contrast, base flow anion deficit was lower in spring and winter, but increased during winter/spring storms. Increased SO4/2- concentration was the main cause of episodic acidification during storms at Reedy Creek, but increased anion deficit indicates organic acids may contribute to episodic acidification during winter/spring storms. Changes in SO4/2- concentration coincident with the hydrograph rise indicate quick routing of water through the watershed. Saturation overland flow appears to be the likely mechanism by which solutes are transported to the stream during storm flow.

Water, Air, & Soil Pollution↗