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A. Jefferson Sutton

Publications and source records attributed to A. Jefferson Sutton.

4 recordsLinked to original sources

Reconnaissance gas measurements on the East Rift Zone of Kilauea Volcano, Hawai'i by Fourier transform infrared spectroscopy

We report the results of a set of measurements of volcanic gases on two small ground level plumes in the vicinity of Pu`u `O`o cone on the middle East Rift Zone (ERZ) of Kilauea volcano, Hawai`i on 15 June 2001 using open-path Fourier transform infrared (FTIR) spectroscopy. The work was carried out as a reconnaissance survey to assess the monitoring and research value of FTIR measurements at this volcano. Despite representing emissions of residual volatiles from lava that has undergone prior degassing, the plumes contained detectable amounts of CO2, CO, SO2, HCl, HF and SiF4. Various processes, including subsurface cooling, condensation of water in the atmospheric plume, oxidation, dissolution in water, and reactions with wall rocks at plume vents affect the abundance of these gases. Low concentrations of volcanic CO2 measured against a high ambient background are not well constrained by FTIR spectroscopy. Although there appear to be some differences between these gases and Pu`u `O`o source gases, ratios of HCl/SO2, HF/SO2 and CO/SO2 determined by FTIR measurements of these two small plumes compare reasonably well with earlier published analyses of ERZ vent samples. The measurements yielded emission rate estimates of 4, 11 and 4 t d-1

Hawaii

Sulfur dioxide emission rates from Kīlauea Volcano, Hawai‘i, an update: 1998-2001

Introduction Sulfur dioxide (SO 2 ) emission rates from Kilauea Volcano were first measured by Stoiber and Malone (1975) and have been measured on a regular basis since 1979 (Greenland and others, 1985; Casadevall and others, 1987; Elias and others, 1998; Sutton and others, 2001). A compilation of SO 2 emission-rate and wind-vector data from 1979 through 1997 is available as Open-File Report 98-462 (Elias and others, 1998) and on the web at http://hvo.wr.usgs.gov/products/OF98462/. The purpose of this report is to update the existing database through 2001. Kilauea releases SO 2 gas predominantly from its summit caldera and east rift zone (ERZ) (fig. 1), as described in previous reports (Elias and others, 1998; Sutton and others, 2001). These two distinct sources are quantified independently. The summit and east rift zone emission rates reported here were derived using vehicle-based Correlation Spectrometry (COSPEC) measurements as described in Elias and others (1998). In 1998 and 1999, these measurements were augmented with airborne and tripod-based surveys.

Hawaii

Rates of volcanic CO 2 degassing from airborne determinations of SO 2 Emission rates and plume CO 2 SO 2 : test study at Pu′u ′O′o Cone, Kilauea Volcano, Hawaii

We present an airborne method that eliminates or minimizes several disadvantages of the customary plume cross-section sampling method for determining volcanic CO 2 emission rates. A LI-COR CO 2 analyzer system (LICOR), a Fourier transform infrared spectrometer system (FTIR), and a correlation spectrometer (COSPEC) were used to constrain the plume CO 2 /SO 2 and the SO 2 emission rate. The method yielded a CO 2 emission rate of 300 td −1 (metric tons per day) for Pu′u ′O′o cone, Kilauea volcano, on 19 September 1995. The CO 2 /SO 2 of 0.20 determined from airborne LICOR and FTIR plume measurements agreed with the CO 2 /SO 2 of 204 ground-based samples collected from vents over a 14-year period since the Pu′u ′O′o eruption began in January 1983.

Geophysical Research Letters

Annotated bibliography of spectrophotometric studies in the system U-Fe-Se-S-O-H, 1967-78

Preparation of this bibliography was originally begun to supply background information on previous ultraviolet and visible spectrophotometric studies on various chemical species thought to be important in the formation of sedimentary uranium deposits; we also thought that preparing the bibliography would help direct experimental efforts to determine the association of iron and uranium with several metastable sulfur species. In compiling these references, however, we found that much work had been done on the chemical species of interest by using types of spectroscopy other than ultraviolet and visible spectrophotometry. The dimensions of the bibliography were therefore broadened to include a wide variety of spectral-measuring techniques to make this report useful to a larger audience.

Open-File Report